MIL-100(Fe)를 함유한 혼합기질막(mixed-matrix membranes, MMMs)의
제조 및 기체 투과 특성 연구

송 혜 림^*,**, 남 승 은^**, 황 영 규^***. 장 종 산^***, 이 우 황^***, 박 유 인^**,†

^*과학기술연합대학원대학교 청정화학 및 생물학, ^**한국화학연구원 자원분리회수연구그룹,
^***한국화학연구원 바이오리파이너리연구그룹

Preparation and Characterization of Mixed-matrix Membranes Containing MIL-100(Fe) for Gas Separation

You In Park^**,†, Hye Rim Song^*,**, Seung Eun Nam^**, Young Kyu Hwang^***, Jong San Chang^***, U Hwang Lee^***

^**Resources Separation and Recovery Research Group, Korea Research Institute of Chemical Technology, Daejeon, Korea
^*Green Chemistry and Environmental Biotechnology, University of Science and Technology, Daejeon, Korea,
^***Bio-refinery Research Group, Korea Research Institute of Chemical Technology, Daejeon, Korea

(Received December 8, 2013, Revised December 18, 2013, Accepted December 20, 2013)

Abstract

Mixed-matrix membranes (MMMs) containing MIL-100(Fe), a MOF type, were fabricated in this study.MMMs up to 30 wt% MOF loading were prepared, and their gas permeabilities were tested. H₂, CO₂, O₂, N₂, and CH₄ gaspermeabilities increased with the MOF loading, while SF₆, the largest kinetic diameter in this study, exhibited reduction ofgas permeability with the loading. Ideal gas selectivity of N₂/SF₆ improved by 40% as compared with pure polyimide membrane,suggesting the proposed MMMs were suitable for N₂/SF₆ separation.

Key Words : MOF,MIL 100(Fe),MMMs,mixed matrix membrane,gas separation membrane

MIL-100(Fe)를 함유한 혼합기질막(mixed-matrix membranes, MMMs)의 제조 및 기체 투과 특성 연구

Preparation and Characterization of Mixed-matrix Membranes Containing MIL-100(Fe) for Gas Separation

Abstract

Reference

MIL-100(Fe)를 함유한 혼합기질막(mixed-matrix membranes, MMMs)의
제조 및 기체 투과 특성 연구