Flaring 가스의 CO2 분리를 위한 분리막 공정 기술개발
Membrane Process Development for CO₂ Separation of Flaring Gas
(Received August 1, 2013, Revised August 29, 2013, Accepted October 7, 2013)
Abstract
We prepared composite membrane which was made with polysulfone supported hollow fiber membrane coatedwith Hyflon AD to eliminate CO2 gas from mixed-gases which were generated in DME manufacturing processes. The performanceof module about simulated flaring gas was measured by using manufactured composite membrane. 1-stage evaluationresult shows CO2 concentration was below 3% at 1.2 MPa and at Stage cut 0.24 above. In addition CO2 removal rateand CH4 recovery rate was 80% respectively at the same condition. 2-stage evaluation result shows, when the CO2 concentrationof product gas was fixed at 5%, recycled CO2 at stage cut 0.074 had the same concentration as the feed gas and therecovery rate of CH4 was 99% at the moment.
- 0098-01-0023-0001-8.pdf5.57MB
Reference
1.C. Hendriks, "Carbon dioxide removal from coal fired power plant", p. 53 Kluwer Academic Publishers, Dordrecht (1994).
2.D. L. Ellig, J. B. Althouse, and F. P. McCandless, "Concentration of methane from mixtures with carbon dioxide by permeation through polymeric films", J. Membr. Sci., 6, 259 (1980).
3.H. Koh, S. Y. Ha, S. M. Woo, S. Y. Nam, B. S. Lee, C. S. Lee, and W. M. Choi, "Separation and purification of biogas by hollow fiber gas separation membrane module", Membrane Journal, 21(2), 177 (2011).
4.H. C. Koh, S. Y. Ha, and S. Y. Nam, "Preparation and Properties of Hollow Fiber Membrane for Gas Separation Using CTA", Membrane Journal, 21, 98 (2010).
5.S. J. Kim, S. M. Woo, H. Y. Hwang, H. C. Koh, S. Y. Ha, H. S. Choi, and S. Y. Nam, "Preparation and Properties of Chlorine- Resistance Loose Reverse Osmosis Hollow- fiber Membrane", Membrane Journal, 20, 304 (2010).
6.I. Pinnau and B. D. Freeman, "Formation and modification of polymieric membranes", American chemical society, Washington DC membr. Sci., 744, 1 (1999).
7.Muller, Dr. Heinz-Joachim and Floyd, Elizabeth, "Modified membrane", Australian patent office AU 2002214802 B2, 7, 25 (2002).
8.J. Phattaranawik, R. Jiraratananon, and A. G. Fane, "Effect of pore size distribution and air flux on mass transport in direct contact membrane distillation", J. Membr. Sci., 215, 75 (2003).
2.D. L. Ellig, J. B. Althouse, and F. P. McCandless, "Concentration of methane from mixtures with carbon dioxide by permeation through polymeric films", J. Membr. Sci., 6, 259 (1980).
3.H. Koh, S. Y. Ha, S. M. Woo, S. Y. Nam, B. S. Lee, C. S. Lee, and W. M. Choi, "Separation and purification of biogas by hollow fiber gas separation membrane module", Membrane Journal, 21(2), 177 (2011).
4.H. C. Koh, S. Y. Ha, and S. Y. Nam, "Preparation and Properties of Hollow Fiber Membrane for Gas Separation Using CTA", Membrane Journal, 21, 98 (2010).
5.S. J. Kim, S. M. Woo, H. Y. Hwang, H. C. Koh, S. Y. Ha, H. S. Choi, and S. Y. Nam, "Preparation and Properties of Chlorine- Resistance Loose Reverse Osmosis Hollow- fiber Membrane", Membrane Journal, 20, 304 (2010).
6.I. Pinnau and B. D. Freeman, "Formation and modification of polymieric membranes", American chemical society, Washington DC membr. Sci., 744, 1 (1999).
7.Muller, Dr. Heinz-Joachim and Floyd, Elizabeth, "Modified membrane", Australian patent office AU 2002214802 B2, 7, 25 (2002).
8.J. Phattaranawik, R. Jiraratananon, and A. G. Fane, "Effect of pore size distribution and air flux on mass transport in direct contact membrane distillation", J. Membr. Sci., 215, 75 (2003).