관형 세라믹 정밀여과와 광촉매 첨가 PES 구의 혼성 수처리: 물 역세척 시 유기물 및 흡착, 광산화의 영향
Hybrid Water Treatment of Tubular Ceramic MF and Photocatalyst Loaded Polyethersulfone Beads: Effect of Organic Matters, Adsorption and Photo-oxidation at Water Back-flushing
(Received April 4, 2013, Revised April 16, 2013, Accepted April 23, 2013)
Abstract
The effect of humic acid (HA), and the roles of microfiltration (MF), PES (polyethersulfone) beads adsorption, and photo-oxidation were investigated in hybrid process of ceramic MF and PES beads loaded with titanium dioxide (TiO2) photocatalyst for advanced drinking water treatment. The results of water and nitrogen back-flushing were compared in viewpoints of membrane fouling resistance (Rf), permeate flux (J), and total permeate volume (VT). Because membrane fouling increased dramatically as increasing HA, Rf increased and J decreased, and finally VT was the highest at 2 mg/L HA. Average turbidity treatment efficiencies were almost same independent of HA concentration. Average organic matter treatment efficiency was the minimum 71.4% at 10 mg/L HA in water back-flushing, but those were almost constant in nitrogen back-flushing. The hybrid process of MF, PES beads, and UV (MF + TiO2 + UV) have the lowest Rf, and the highest J and VT in both water and nitrogen back-flushing. The turbidity and organic matter treatment efficiencies were the maximum at MF + TiO2 + UV independent of water and nitrogen back-flushing, and decreased sequently as simplifying the process to MF. However, adsorption performed the more important role than photo-oxidation in water back-flushing, and photo-oxidation was the more than adsorption in nitrogen back-flushing.
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